Affiliation:
1. Department of Mechanical and Industrial Engineering University of Illinois Chicago Chicago IL 60607 USA
2. Department of Aerospace and Mechanical Engineering University of Arizona Tucson AZ 85721 USA
Abstract
AbstractUnderstanding the thermal decomposition of metal salt precursors on carbon structures is essential for the controlled synthesis of metal‐decorated carbon nanomaterials. Here, the thermolysis of a Ni precursor salt, NiCl2·6H2O, on amorphous carbon (a‐C) and graphene oxide (GO) substrates is explored using in situ transmission electron microscopy. Thermal decomposition of NiCl2·6H2O on GO occurs at higher temperatures and slower kinetics than on a‐C substrate. This is correlated to a higher activation barrier for Cl2 removal calculated by the density functional theory, strong Ni‐GO interaction, high‐density oxygen functional groups, defects, and weak van der Waals using GO substrate. The thermolysis of NiCl2·6H2O proceeds via multistep decomposition stages into the formation of Ni nanoparticles with significant differences in their size and distribution depending on the substrate. Using GO substrates leads to nanoparticles with 500% smaller average sizes and higher thermal stability than a‐C substrate. Ni nanoparticles showcase the fcc crystal structure, and no size effect on the stability of the crystal structure is observed. These findings demonstrate the significant role of carbon substrate on nanoparticle formation and growth during the thermolysis of carbon–metal heterostructures. This opens new venues to engineer stable, supported catalysts and new carbon‐based sensors and filtering devices.
Funder
National Science Foundation
Subject
Electrochemistry,Condensed Matter Physics,Biomaterials,Electronic, Optical and Magnetic Materials
Cited by
4 articles.
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