Electrocatalytic dehalogenation in the applications of organic synthesis and environmental degradation

Author:

Zhao Zhefei123,Yao Xuyao1,Zhang Linlin1,Yu Ruopeng1,Xu Yinghua123,Chu Youqun123,Mao Xinbiao12,Zheng Huajun123ORCID

Affiliation:

1. Department of Applied Chemistry Zhejiang University of Technology Hangzhou China

2. Petroleum and Chemical Industry Key Laboratory of Organic Electrochemical Synthesis State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology Zhejiang University of Technology Hangzhou China

3. Research Institute of Zhejiang University of Technology‐Taizhou Taizhou China

Abstract

AbstractElectrocatalytic dehalogenation technology is a promising approach for the synthesis of chemicals (such as pesticides and pharmaceutical intermediates) and the disposal of halogenated organic pollutants. Compared with the traditional chemical reduction technology, the electrocatalytic reduction dehalogenation method has the advantages of high efficiency, controllable operation, and reduced secondary pollution. This review systematically consolidates the recent advances in the electrocatalytic dehalogenation in the application of organic synthesis and environmental degradation, focusing on the involved mechanisms, and influences factors (e.g., electrocatalysts, solution environment, and reaction conditions) on the performance of electrocatalytic dehalogenation. Furthermore, the latest characterization and analytical methods and the industrial application of electrocatalytic dehalogenation technology are summarized. Lastly, the existing challenges and perspectives are proposed for efficient electrocatalytic dehalogenation.

Publisher

Wiley

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