Plasma polymerization of allyltrimethylsilane with single‐filament dielectric‐barrier discharges—Evidence of cationic surface processes

Author:

Bröcker Lars1ORCID,Winzer Tristan2,Steppan Nickolas1,Benedikt Jan2ORCID,Klages Claus‐Peter1ORCID

Affiliation:

1. Institute for Surface Technology, IOT Technische Universität Braunschweig Braunschweig Germany

2. Institute of Experimental and Applied Physics Faculty of Mathematics and Natural Sciences Kiel Germany

Abstract

AbstractAtmospheric‐pressure plasma‐enhanced film deposition with single‐filament dielectric‐barrier discharges (DBDs) in argon was investigated using allyltrimethylsilane (ATMS) as a precursor. Nonionic deposition in the discharge zone is largely precluded by a rapid cross‐flow of the source gas, containing between 50 and 2000 ppm of ATMS. The performed experimental studies show a surprisingly large deposited film mass per transferred elementary charge between 220 and 540 amu. Film growth experiments, mass‐spectrometric studies, and kinetic considerations led to the conclusion that the deposition process is a cationic surface polymerization, initiated by ions produced in the DBD by energy transfer from long‐lived excited Ar species and propagated by addition of ATMS monomer molecules.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Wiley

Subject

Polymers and Plastics,Condensed Matter Physics

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