Cyclometalation of Phosphanes at Iridium(I): Interplay with Intramolecular Reductive Elimination Induced by the Strong π‐Acceptor Ligands CO and NO +
Author:
Affiliation:
1. Department Chemie, Ludwig‐Maximilians‐Universität München, Butenandtstraße 5‐13, 81377 München, http://www.cup.uni‐muenchen.de
Publisher
Wiley
Subject
Inorganic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.201500363
Reference17 articles.
1. Synthesis and Molecular Structure oftrans-[IrCl(coe)(tBu2PH)2] (coe =cis-cyclooctene)
2. Iridium complexes with secondary phosphines: synthesis and X-ray crystal structure of [IrCl(Bu2tPH)3]
3. Identification of an elusive catalyst: IrH(η2-C6H4PtBu2) (Cl)(PtBu2Ph) as a precursor for C=C bond migration
4. Convenient Synthesis and Molecular Structure of the Cyclometallated Complex [IrCl(H)(C6H4PPh2)(PPh3)2]
5. A Case of C−H Activation (Ortho Metalation) Which Is Reversible at 25 °C
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1. Remarkably Efficient Iridium Catalysts for Directed C(sp2)–H and C(sp3)–H Borylation of Diverse Classes of Substrates;Journal of the American Chemical Society;2021-03-30
2. Spontaneous Reductive Elimination at Iridium(III) Induced by the Strong π‐Acceptor Ligand Trifluorophosphane;Zeitschrift für anorganische und allgemeine Chemie;2020-04-14
3. Crystal and molecular structure of trans-[RhCl(CO)(P t Bu2Ph)2];Zeitschrift für Naturforschung B;2018-10-04
4. Synthesis and Molecular Structure oftrans-[IrCl(NO)(PtBu2H)2]BF4;Zeitschrift für anorganische und allgemeine Chemie;2016-07
5. Synthesis and Molecular Structure oftrans-[RhCl(NO)(PtBu2H)2]BF4;Zeitschrift für anorganische und allgemeine Chemie;2016-02
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