Synthetic and Structural Study on Orthometallated Ferrocene Complexes: Non‐Planar Metallabenzene and Five‐Membered Metallacycle Complexes with Closed Os 3 Triangles-Reference-Cited by-同舟云学术

Synthetic and Structural Study on Orthometallated Ferrocene Complexes: Non‐Planar Metallabenzene and Five‐Membered Metallacycle Complexes with Closed Os 3 Triangles

Published:2018-07-05 Issue:26 Volume:2018 Page:3126-3130
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur. J. Inorg. Chem.

Author:

Tauqeer Mohd.¹²,Ji Radhe Shyam³,Singh Amrendra K.³,Mobin Shaikh M.⁴,Lahiri Goutam K.¹,Mathur Pradeep¹³⁴^ORCID

Affiliation:

1. Department of Chemistry Indian Institute of Technology Bombay Powai 400076 Mumbai India

2. Department of Chemistry Aligarh Muslim University 202002 Aligarh India

3. School of Basic Sciences Indian Institute of Technology Indore 453552 Simrol Indore India

4. Sophisticated Instrument Center Indian Institute of Technology Indore Simrol 453552 Indore India

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.201800252

Reference45 articles.

1. Ferrocyne and ferrodicyne. Preparation and structures of Os3(CO)s[.mu.3-(C5H3)Fe(C5H5)][.mu.3-P(C5H4)Fe(C5H5)], Os3(H)2(CO)8(PPr-iso2C5H2)Fe(C5H2PPr-iso2)Os3(H)2(CO)8, and Os3(CO)9[.mu.3-C6H4][.mu.3-P(C5H4)Fe(C5H5)]

2. Iron-osmium bonding in clusters containing ferrocene fragments

3. Double metalation and iron-osmium bonding involving ferrocenyl moieties on clusters. Crystal and molecular structures of H2Os3(CO)8[(.eta.-C5H4)Fe(.eta.-C5H3PPr2-iso)] and H2Os3(CO)8[(.eta.-C5H4)Fe(.eta.-C5H3PFcEt)]

4. Preparation and characterization of the osmium cluster complexes H2Os3(CO)8L(EtFcPCMe) (L = CO or PEt2Fc) and H2Os3(CO)8[(η-C5H3PEt2)Fe(η-C5H4)]

5. Crystal and molecular structures of Os3(CO)9[μ3-(C5H4PR)Fe(C5H4)] (R  Fc or Ph), two molecules with Fe → Os bonds

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