New Insight into a Deceptively Simple Reaction: The Coordination of bpy to Ru II –Carbonyl Precursors – The Central Role of the fac ‐[Ru(bpy)Cl(CO) 3 ] + Intermediate and the Chloride Rebound Mechanism-Reference-Cited by-同舟云学术

New Insight into a Deceptively Simple Reaction: The Coordination of bpy to Ru II –Carbonyl Precursors – The Central Role of the fac ‐[Ru(bpy)Cl(CO) 3 ] + Intermediate and the Chloride Rebound Mechanism

Published:2015-08-21 Issue:26 Volume:2015 Page:4296-4311
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur. J. Inorg. Chem.

Author:

Balducci Gabriele¹,Iengo Elisabetta¹,Demitri Nicola²,Alessio Enzo¹

Affiliation:

1. Dipartimento di Scienze Chimiche e Farmaceutiche, Università di Trieste Via L. Giorgieri 1, 34127 Trieste, Italy, http://dscf.units.it/en/department/people/alessio‐enzo/1055

2. Elettra – Sincrotrone Trieste S. S. 14 Km 163.5 in Area Science Park, 34149 Basovizza, Trieste, Italy

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.201500568

Reference79 articles.

1. Electrochemical CO2 reduction catalyzed by ruthenium complexes [Ru(bpy)2(CO)2]2+ and [Ru(bpy)2(CO)Cl]+. Effect of pH on the formation of CO and HCOO-

2. Photochemical reduction of carbon dioxide to formate catalyzed by 2,2t́-bipyridine- or 1,10-phenanthroline-ruthenium(II) complexes

3. Photochemical carbon dioxide reduction catalyzed by bis(2,2'-bipyridine)dicarbonylruthenium(2+) using triethanolamine and 1-benzyl-1,4-dihydronicotinamide as an electron donor

4. Ligand effects of ruthenium 2,2′-bipyridine and 1,10-phenanthroline complexes on the electrochemical reduction of CO2

5. Comparative study on crystal structures of ruthenium bipyridine carbonyl complexes [Ru(bpy)2(CO)2](PF6)2, [Ru(bpy)2(CO)(C(O)OCH3)]B(C6H5)4.cntdot.CH3CN, and [Ru(bpy)2(CO)(.eta.1-CO2)].cntdot.3H2O (bpy = 2,2'-bipyridyl)

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