One‐Step Synthesis and Deposition of Metal Oxides: NiO Quantum Dots as a Transport Layer for Perovskite Photovoltaics

Author:

Padmanaban Dilli babu1ORCID,Sadhu Subha12,Dsouza Slavia Deeksha1,Mushtaq Warda3,Holman Zachary3,Svrcek Vladimir4,Mariotti Davide5ORCID

Affiliation:

1. Plasma Science and Nanoscale Engineering Group Ulster University Belfast BT15 1AP UK

2. Department of Chemistry Institute of Science Banaras Hindu University Varanasi 221005 India

3. School of Electrical, Computer, and Energy Engineering Arizona State University Tempe AZ 85287‐5706 USA

4. National Institute of Advanced Industrial Science and Technology (AIST) Central 2 Umezono 1‐1‐1 Tsukuba Ibaraki 305‐8568 Japan

5. Department of Design, Manufacturing and Management Engineering University of Strathclyde Glasgow G1 1XJ UK

Abstract

One‐step synthesis and deposition of nickel oxide quantum dots using a gas‐phase microplasma process is demonstrated and their applicability as a transport layer for solar cell devices is shown. The process uses a solid nickel metal wire as sacrificial electrode, and the concentration of oxygen gas required in the synthesis is investigated. The quantum dots are characterized for physical, chemical, and optical properties and critical process parameters such as the process throughput are also estimated. Direct one‐step deposition directly on perovskite solar cells is carried out using a computer‐controlled xy stage and the performance of the solar cell device is assessed.

Funder

Engineering and Physical Sciences Research Council

Publisher

Wiley

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