Unveiling the Intricacies of a Ductile‐Phase Toughened Intermetallic: An In‐Depth Exploration of a Eutectic Mo–Si–Ti Alloy and its Mechanical Behavior

Author:

Vikram Raja Jothi12,Aramanda Shanmukha Kiran1,Schliephake Daniel2,Kauffmann Alexander2ORCID,Choudhury Abhik1,Heilmaier Martin2,Suwas Satyam1

Affiliation:

1. Department of Materials Engineering Indian Institute of Science Bangalore 560012 India

2. Institute for Applied Materials (IAM‐WK) Karlsruhe Institute of Technology (KIT) 76131 Karlsruhe Germany

Abstract

Herein, the development of directional solidification for a novel high‐temperature Mo–20Si–52.8Ti (at%) ternary alloy using a modified Bridgeman type apparatus is presented. The resulting alloy exhibits a microstructure consisting of a body‐centered cubic solid solution (BCCss) and a hexagonal silicide (Ti,Mo)5Si3 with approximate volume fractions of 50% for each phase. The phases exhibit a crystallographic orientation relationship with and . Different solidification velocities are imposed, which reveal an inverse relationship to the lamellar spacing according to a Jackson–Hunt type scaling. Mechanical characterization using Vickers indentation demonstrates that the BCCss accommodates plasticity through dislocation motion, while the silicide phase exhibits high hardness and brittleness, serving as a crack initiation site. Crack propagation is arrested and deflected at the interface to the BCCss. Fracture toughness measurements via indentation yield a fracture toughness of 3.7 MPa√m for the silicide, somewhat higher than previously reported values for Nb‐, Mo‐, and Cr‐based silicides at room temperature. The directionally solidified specimens show an enhanced fracture toughness attributed to a greater BCCss length scale; thus, combining the ductile and hard phases results in a ductile‐phase toughened intermetallic composite. The findings open up new possibilities for the design of advanced intermetallic composites with improved toughness performance.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Wiley

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