Optical Evidence of Compositional Fractioning between Plasma‐Condensed and Melt Pool Matter

Author:

Hubbard Lance1ORCID,Hilty Floyd1ORCID,Roy Ankit1ORCID,Miley Sarah1ORCID,Overman Nicole1ORCID,Muller Scott1ORCID,Fiedler Kevin R.1ORCID,Horangic Diana1ORCID,Olszta Matt1ORCID

Affiliation:

1. Engineered and Computational Materials Team Pacific Northwest National Laboratory P.O. Box 999 Richland 99352 WA USA

Abstract

Control of multicomponent alloys during welding is challenging because it lacks a real‐time understanding of composition. The optical emissions of plasma formed during laser‐induced metal welding correlate with the composition of particles ejected from the melt pool. Plasma emissions observed in this study contain large iron, manganese, chrome, and copper signatures, which match the composition of emitted particles. Particles recovered closest to the melt pool exhibit a core–shell morphology that is composed of iron‐manganese‐chrome intermetallic cores within copper shells. Particles collected farther from the melt pool, do not share this core–shell morphology, though similar elemental compositions are observed. The correlation between plasma optical emissions and particle composition can be used to predict the composition of the melt pool, allowing for real‐time welding and sintering control.

Funder

Laboratory Directed Research and Development

Pacific Northwest National Laboratory

U.S. Department of Energy

Publisher

Wiley

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