Enhancement of intermolecular aggregation on solvent‐influenced strong hydrogen‐bonded single crystal

Author:

Rajakumar Kanthapazham1ORCID,Nekorysnova Nadezhda S.1,Dorovatovskii Pavel V.2,Osipov Artyom A.1,Nayfert Sergei A.1,Efremov Andrey N.1,Santhanaraj Daniel3,Ramkumar Vanaraj4,Tolstoguzov Dmitry S.1,Zherebtsov Dmitry A.1

Affiliation:

1. South Ural State University National Research University Chelyabinsk Russia

2. Department of Synchrotron Experimental Stations National Research Center Kurchatov Institute Moscow Russia

3. Department of Chemistry Loyola College Chennai India

4. School of Chemical Engineering Yeungnam University Gyeongsan Republic of Korea

Abstract

AbstractThe intermolecular aggregation between the solvent and organic molecules is covered in the current article. 4,4′‐(Buta‐1,3‐diyne‐1,4‐diyl)dibenzoic acid (DADBA) was used as an organic molecule and dimethyl sulfoxide (DMSO) as a solvent to create the target compound DADBA‐DMSO. The material's hydrogen bonding and intermolecular aggregation were determined by appropriate characterization methods, including single‐crystal X‐ray diffraction (XRD), Fourier‐transform infrared (FTIR), photoluminescence (PL), and cyclic voltammetry (CV) analysis. Each hydrogen of the carboxylic group is coordinated by oxygen from the DMSO molecule in the stiff planar layer packing that makes up the DADBA‐DMSO crystal structure.

Funder

Russian Science Foundation

Publisher

Wiley

Subject

Chemistry (miscellaneous),Biophysics

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3