Affiliation:
1. Department of Fundamental Chemistry, Institute of Chemistry University of São Paulo São Paulo State of São Paulo Brazil
Abstract
AbstractNMR spectroscopy has become a standard technique in studies both on carbon capture and storage. 13C NMR allows the detection of two peaks for carbonated aqueous samples: one for CO2(aq) and another one for the species H2CO3, HCO3−, and CO32−—herein collectively named HxCO3x‐2. The chemical shift of this second peak depends on the molar fraction of the three species in equilibrium and has been used to assess the equilibrium between HCO3− and CO32−. The detection of H2CO3 at low pH solutions is hindered, because of the concurrent liberation of CO2 when the medium is acidified. Herein, a valved NMR tube facilitates the detection of the HxCO3x‐2 peak across a wide pH range, even at pH 1.8 where the dominant species is H2CO3. The method employed the formation of frozen layers of NaH13CO3 and acid solutions within the tube, which are mixed as the tube reaches room temperature. At this point, the tube is already securely sealed, preventing any loss of CO2 to the atmosphere. A spectrophotometry approach allowed the measurement of the actual pH inside the pressurized NMR tube. The chemical shift for H2CO3 was determined as 160.33 ± 0.03 ppm, which is in good agreement with value obtained by DFT calculations combined with Car–Parrinello molecular dynamics. The H2CO3 pKa value determined by the present method was 3.41 ± 0.03, for 15% D2O aqueous medium and 0.8 mol/L ionic strength. The proposed method can be extended to studies about analogs such as alkyl carbonic and carbamic acids.
Funder
Fundação de Amparo à Pesquisa do Estado de São Paulo
Conselho Nacional de Desenvolvimento Científico e Tecnológico