Straightforward Synthesis of a Vicinal Double-Bridgehead Iodo Trimethylsilyl Octacycle: Unprecedented Lack of Reactivity of the Silyl Group in the Presence of Fluoride Anions-Reference-Cited by-同舟云学术

Straightforward Synthesis of a Vicinal Double-Bridgehead Iodo Trimethylsilyl Octacycle: Unprecedented Lack of Reactivity of the Silyl Group in the Presence of Fluoride Anions

Published:2017-03-27 Issue:12 Volume:2017 Page:1594-1603
ISSN:1434-193X
Container-title:European Journal of Organic Chemistry
language:en
Short-container-title:Eur. J. Org. Chem.

Author:

Camps Pelayo¹^ORCID,Lozano David¹^ORCID,Guitián Enrique²^ORCID,Peña Diego²^ORCID,Pérez Dolores²^ORCID,Font-Bardia Mercè³⁴^ORCID,Llamas-Saíz Antonio L.⁵^ORCID

Affiliation:

1. Laboratori de Química Farmacèutica (Unitat Associada al CSIC); Facultat de Farmàcia i Ciències de la Alimentació and Institut de Biomedicina (IBUB); Universitat de Barcelona; Av. Joan XXIII 27-31 08028 Barcelona Spain

2. Centro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS) and Departamento de Química Orgánica; Universidade de Santiago de Compostela; 15782 Santiago de Compostela Spain

3. Departament de Cristal·lografia; Mineralogia I Dipòsits Minerals; Universitat de Barcelona; Martí Franquès s/n 08028 Barcelona Spain

4. Unitat de Difracció de RX; Centres Científics I Tecnològics de la Universitat de Barcelona (CCiTUB); Solé i Sabarís 1-3 08028 Barcelona Spain

5. Unidade de Raios X. RIAIDT; Edificio CACTUS; Universidade de Santiago de Compostela; Campus Vida 15782 Santiago de Compostela Spain

Funder

Secretary of State of Research, Development and Innovation

Agència de Gestió d’Ajuts Universitaris i de Recerca

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

Reference47 articles.

1. Pyramidalized alkenes

2. Synthesis of Alkenes with Pyramidalized Double Bonds - Unnatural Products of Theoretical Interest

3. Unsaturated dodecahedranes—Synthesis of the highly pyramidalized, highly reactive C20H18 and C20H16 olefins

4. Chemistry of pyramidalized alkenes

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