Alkynylation of Aldehydes Initiated by Cathodic Reduction-Reference-Cited by-同舟云学术

Alkynylation of Aldehydes Initiated by Cathodic Reduction

Published:2023-12-12 Issue:1 Volume:11 Page:
ISSN:2196-0216
Container-title:ChemElectroChem
language:en
Short-container-title:ChemElectroChem

Author:

Sato Eisuke¹^ORCID,Fujii Mayu¹,Mitsudo Koichi¹^ORCID,Suga Seiji¹^ORCID

Affiliation:

1. Division of Applied Chemistry Graduate School of Environmental, Life Natural Science and Technology Okayama University 3-1-1, Tsushima-naka, Kita-ku Okayama 700-8530 Japan

Abstract

AbstractAlkynylation of aldehydes initiated by cathodic reduction was performed. The cathodic alkynylation required only a semi‐catalytic amount of electricity to consume the starting material completely. Cyclic voltammetry and some control experiments suggest that the electron‐generated base derived from the cathodic reduction of benzaldehyde promotes alkynylation.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Wiley

Subject

Electrochemistry,Catalysis

Reference89 articles.

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4. Enantioselective Addition of Terminal Alkynes to Aldehydes Catalyzed by a Cu(I)−TRAP Complex

5. Asymmetric Direct Alkynylation Catalyzed by Chiral Ru−Bis(oxazolinyl)phenyl Complexes

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