Incorporating Gadolinium Oxide (Gd2O3) as a Rare Earth Metal Oxide in Carbon Nanofiber Skeleton for Supercapacitor Application

Author:

Aydın Hamide1ORCID,Üstün Burcu2,Kurtan Ümran3,Aslan Ayşe45,Karakuş Selcan1

Affiliation:

1. Department of Chemistry İstanbul University-Cerrahpaşa 34500 İstanbul/ Turkey

2. Department of Chemical Engineering İstanbul University-Cerrahpaşa 34500 İstanbul/ Turkey

3. Department of Materials and Materials Processing Technologies Vocational School of Technical Sciences İstanbul University-Cerrahpaşa 34500 İstanbul/ Turkey

4. Department of Bioengineering Gebze Technical University 41400 Kocaeli/ Turkey

5. Institute of Energy Technologies Gebze Technical University 41400 Kocaeli/ Turkey

Abstract

AbstractIn this study, we synthesized gadolinium oxide nanoparticles (Gd2O3 NPs) incorporated heteroatom‐doped microporous carbon nanofibers (CNF) to serve as electrode materials for enhancing supercapacitive energy storage. Our primary focus is on elucidating the impact of these hybrid electrode materials on key supercapacitor performance properties such as specific capacitance, specific energy, and specific power. To comprehensively assess the structural and chemical attributes of Gd2O3 NPs‐incorporated heteroatom‐doped microporous CNFs (CNF/Gd2O3) we employed an array of advanced characterization techniques, including scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy (RAMAN), X‐ray diffraction (XRD), and X‐ray photoelectron spectroscopy (XPS). Our research has yielded impressive results, demonstrating a significant increase in supercapacitive performance. Specifically, the CNF/Gd2O3‐1 symmetric supercapacitor cell (SSC) has demonstrated a good specific capacitance of 162.3 F/g and a high specific energy of 8.12 Wh/kg at a specific power of 300 W/kg. These findings could be a new pathway to prepare composite electrodes for use in energy storage applications and promote further development for other rare‐earth nanostructures.

Publisher

Wiley

Subject

Electrochemistry,Catalysis

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