Late‐stage Ligand Modification After Coordination Strengthens Stereoselectively Self‐Assembled Hemiaminal Ether Complexes-Reference-Cited by-同舟云学术

Late‐stage Ligand Modification After Coordination Strengthens Stereoselectively Self‐Assembled Hemiaminal Ether Complexes

Published:2023-09-15 Issue:20 Volume:18 Page:
ISSN:1861-4728
Container-title:Chemistry – An Asian Journal
language:en
Short-container-title:Chemistry An Asian Journal

Author:

Raje Sakthi¹^ORCID,Koner Abhishek¹^ORCID,Ghosh Suchismita¹^ORCID,Butcher Ray J.²^ORCID,Mathivathanan Logesh³^ORCID,Sundararajan Mahesh⁴^ORCID,Angamuthu Raja¹⁵^ORCID

Affiliation:

1. Department of Chemistry Indian Institute of Technology Kanpur Kanpur 208016 India

2. Department of Chemistry Howard University Washington, D.C. 20059 USA

3. Department of Chemistry School of Advanced Sciences Vellore Institute of Technology Vellore Tamil Nadu 632014 India

4. Theoretical Chemistry Section Chemistry Division Bhabha Atomic Research Centre Mumbai-400085 (India) Homi Bhabha National Institute Mumbai 400085 India

5. Department of Sustainable Energy Engineering Indian Institute of Technology Kanpur Kanpur 208016 India

Abstract

AbstractFragile hemiaminal ether linkages present in the backbone of koneramines (LROR’), tridentate ligands, bound to copper(II) in stereoselectively self‐assembled syn‐[Cu(LROR’)X2] complexes were transformed into sturdy methylene linkages to make corresponding rac‐[Cu(LRH)Cl2] complexes by late‐stage ligand modification after coordination with the retention of coordination sphere. The generality of stereoselective self‐assembly of koneramine complexes is shown by utilising a number of metal ions, anions, amines, alcohols and thiols with complete characterisations.

Funder

Science and Engineering Research Board

Ministry of Higher Education and Scientific Research

Publisher

Wiley

Subject

General Chemistry,Biochemistry,Organic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/asia.202300706

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