Affiliation:
1. School of Chemical Sciences National Institute of Science Education and Research (NISER) An OCC of Homi Bhabha National Institute Bhubaneswar 752050 India
Abstract
AbstractA catalytic method for the direct synthesis of oximes from alcohols and hydroxyl amine hydrochloride salt is reported. The reaction is catalyzed by a ruthenium pincer catalyst, which oxidizes alcohols involving amine‐amide metal‐ligand cooperation, and the in situ formed aldehydes condense with hydroxyl amine to deliver the oximes. Notably, the reaction requires only a catalyst and base; water and liberated hydrogen are the only byproducts, making this protocol attractive and environmentally benign.
Funder
Department of Atomic Energy, Government of India
Subject
General Chemistry,Biochemistry,Organic Chemistry
Cited by
1 articles.
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