Affiliation:
1. Drug Synthesis Engineering Technology Research Center of Henan Province for Photoelectric Green Catalysis Engineering Technology Research Center of Henan Province for Solar Catalysis College of Chemistry and Pharmaceutical Engineering Nanyang Normal University Henan 473061 China
2. State Key Laboratory of Motor Vehicle Biofuel Technology Henan Tianguan Enterprise Group Company Limited Henan 473000 China
Abstract
AbstractA palladium‐catalyzed reaction for intermolecular selective C−H cyclocarbonylation of 2‐iodobiphenyls is described. Intriguingly, the vinylene carbonate acts as a carbon monoxide transfer agent to enable the annulation reaction. Moreover, as a versatile synthon, fluoren‐9‐one can be transformed into a variety of functionalized organic molecules, such as [1,1′‐biphenyl]‐2‐carboxylic acid, 1′H,3′H‐spiro[fluorene‐9,2′‐perimidine] and N‐tosylhydrazones.
Subject
General Chemistry,Biochemistry,Organic Chemistry
Cited by
1 articles.
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