Cationic Iridium‐Catalyzed Decarboxylation of Aromatic Carboxylic Acids-Reference-Cited by-同舟云学术

Cationic Iridium‐Catalyzed Decarboxylation of Aromatic Carboxylic Acids

Published:2023-07-27 Issue:17 Volume:18 Page:
ISSN:1861-4728
Container-title:Chemistry – An Asian Journal
language:en
Short-container-title:Chemistry An Asian Journal

Author:

Nonami Reina¹,Kishino Yu¹,Yamasaki Tomokazu¹,Kanemoto Kazuya²^ORCID,Iwai Kento³^ORCID,Nishiwaki Nagatoshi³^ORCID,Shibatomi Kazutaka⁴^ORCID,Shirai Tomohiko¹^ORCID

Affiliation:

1. Department of Social Design Engineering National Institute of Technology Kochi College 200-1 Monobe Otsu Nankoku Kochi 783-8508 Japan

2. Graduate School of Pharmaceutical Sciences Tohoku University 6-3 Aoba, Aramaki, Aoba-ku Sendai Miyagi 980-8578 Japan

3. School of Engineering Science Kochi University of Technology, Tosayamada Kami Kochi 782-8502 Japan

4. Department of Applied Chemistry and Life Science Toyohashi University of Technology 1-1 Hibarigaoka, Tempaku-cho Toyohashi Aichi 441-8580 Japan

Abstract

AbstractPractical synthetic applications of catalytic decarboxylation in producing useful molecules are limited. We report herein the cationic Ir‐catalyzed decarboxylations of various electron‐rich and ‐poor aromatic carboxylic acids to produce hydrocarbons in good yield (up to >99%). Additionally, this reaction is applicable in decarboxylative hydroarylation of bicyclic alkenes and decarboxylative fluorination, indicating the potential utility of this catalytic decarboxylation in synthetic chemistry.

Funder

Toyohashi University of Technology

National Institute of Technology, Raipur

Iwatani Naoji Foundation

Publisher

Wiley

Subject

General Chemistry,Biochemistry,Organic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/asia.202300533

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