DMSO‐Assisted K<sub>3</sub>PO<sub>4</sub>‐Catalyzed Cooperative Metal‐Free, Base‐Free Etherification of Chloroheteroarenes at Low Temperature-Reference-Cited by-同舟云学术

DMSO‐Assisted K₃PO₄‐Catalyzed Cooperative Metal‐Free, Base‐Free Etherification of Chloroheteroarenes at Low Temperature

Published:2023-07-07 Issue:16 Volume:18 Page:
ISSN:1861-4728
Container-title:Chemistry – An Asian Journal
language:en
Short-container-title:Chemistry An Asian Journal

Author:

Khandagale Deepali¹,Kori Santosh¹²,Kapdi Anant R.¹

Affiliation:

1. Department of Chemistry Institute of Chemical Technology Nathalal Parekh Road, Matunga Mumbai 400019 India

2. Department of Chemistry Institute of Chemical Technology-Indian Oil Odisha Campus IIT Kharagpur Extension Centre, Mouza Samantpuri Bhubaneswar 751013 Odisha India

Abstract

AbstractEtherification of chloroheteroarenes was performed at low temperatures under metal‐free, ligand‐free and base‐free conditions, that is, the reaction is promoted by the cooperative effect of DMSO (solvent) as a promoter and K3PO4 providing the catalytic surface (rather than a base). The protocol exhibits good substrate scope under mild reaction conditions and has also been explored mechanistically.

Publisher

Wiley

Subject

General Chemistry,Biochemistry,Organic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/asia.202300377

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