Paddle‐Wheel Dirhodium Complexes Bearing Bulky Carboxylate Ligands: Synthesis and Catalysis in Carbene Insertion Reactions-Reference-Cited by-同舟云学术

Paddle‐Wheel Dirhodium Complexes Bearing Bulky Carboxylate Ligands: Synthesis and Catalysis in Carbene Insertion Reactions

Published:2023-04-25 Issue:11 Volume:18 Page:
ISSN:1861-4728
Container-title:Chemistry – An Asian Journal
language:en
Short-container-title:Chemistry An Asian Journal

Author:

Yamashita Kotaro¹,Sato Kota¹,Tanji Yutaka¹,Hasegawa Jun‐ya²,Fujihara Tetsuaki¹^ORCID

Affiliation:

1. Department of Energy and Hydrocarbon Chemistry Graduate School of Engineering Kyoto University Kyoto 615-8510 Japan

2. Institute for Catalysis Hokkaido University Sapporo 001-0021 Japan

Abstract

AbstractDirhodium complexes bearing bulky carboxylate ligands are synthesized and characterized. The steric bulk of carboxylate ligands could affect the reaction selectivity in Rh‐catalyzed intramolecular reactions: Rh catalysts with bulky carboxylate ligands provided five‐membered ring products preferentially via the insertion into a carbon–hydrogen bond. Meanwhile, six‐membered ring products were obtained using conventional Rh catalysts via the insertion of a carbon‐carbon double bond.

Publisher

Wiley

Subject

General Chemistry,Biochemistry,Organic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/asia.202300223

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5. Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes