From Textile Coloring to Light‐emitting Electrochemical Devices: Upcycling of the Isoviolanthrone Vat Dye

Author:

Ghanem Tatiana1,Leong Kwang Keat2,Jang Hwandong2,Hardouin Alexis1,Blanchard Philippe1,Lungerich Dominik34,Josse Pierre15,Kim Eunkyoung25,Cabanetos Clément5ORCID

Affiliation:

1. University of Angers CNRS MOLTECH-ANJOU SFR MATRIX F-49000 Angers France

2. Department of Chemical and Biomolecular Engineering Yonsei University 50 Yonsei-ro, Seodaemun-gu 03722 Seoul South Korea

3. Center for Nanomedicine (CNM) Institute for Basic Science (IBS) IBS Hall, 50 Yonsei-ro, Seodaemun-gu 03722 Seoul South Korea

4. Graduate Program of Nano Biomedical Engineering (NanoBME) Advanced Science Institute Yonsei University 50 Yonsei-ro, Seodaemun-gu 03722 Seoul South Korea

5. Building Blocks for FUture Electronics Laboratory (2BFUEL) IRL2002 CNRS-Yonsei University Seodaemun-gu 03722 Seoul South Korea

Abstract

AbstractProduced at ton scale, vat dyes are major environmental pollutants generated by the textile industry. However, they represent ideal and accessible candidates for chemical upcycling since they are usually composed of large π‐conjugated scaffolds. Based on the valorization of “old” products, waste or even contaminant into high‐added value goods, this concept can be easily transposed to the laboratories. As a contribution to the current environmental and ecological transition, we demonstrate herein the valorization/upcycling of wastewaters generated during the dyeing procedure. To do so, the reduced (leuco) form of vat violet 10, also known as isoviolanthrone, was functionalized to afford a readily soluble derivative that was subsequently and successfully used as active material in operating solution processed light‐emitting electrochemical cells, that is, from textile dyeing to high‐tech application.

Funder

Institute for Basic Science

Ministry of Science, ICT and Future Planning

Publisher

Wiley

Subject

General Chemistry,Biochemistry,Organic Chemistry

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