Affiliation:
1. Department of Chemistry Key Laboratory of Advanced Energy Materials Chemistry Ministry of Education) and Renewable Energy Conversion and Storage Center College of Chemistry Nankai University 300071 Tianjin China
2. Haihe Laboratory of Sustainable Chemical Transformations 300192 Tianjin China
Abstract
AbstractMetal‐complex‐based materials for lithium storage have attracted great interest due to their highly designable structures with multiple active sites and well‐defined lithium transport pathways. Their cycling and rate performances, however, are still constrained by structural stability and electrical conductivity. Herein, we present two hydrogen‐bonded complex‐based frameworks with excellent lithium storage capability. Multiple hydrogen bonds among the mononuclear molecules result in three‐dimensional frameworks that are stable in electrolyte. The origin of the remarkable lithium storage performance of this family was revealed through kinetic analysis and DFT calculations.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Tianjin City
Ministry of Education of the People's Republic of China
Subject
General Chemistry,Biochemistry,Organic Chemistry
Cited by
4 articles.
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