Affiliation:
1. College of Chemical Engineering Hebei Normal University of Science and Technology 066004 Qinhuangdao Hebei China
2. College of Horticultural Science &Technology Hebei Normal University of Science and Technology Qinhuangdao Hebei 066004 China
Abstract
AbstractThe shuttle effect of lithium‐sulfur (Li−S) batteries and the poor conductivity of sulfur (S) and lithium polysulfide severely limit their practical applications. Currently, compounding carbon materials with S is one of the effective ways to solve this problem. Therefore, green, low‐cost chestnut inner shell biochar (CISC) with graded porous structure was used as the S carrier in this experiment, and carbon nanotubes (CNTs) coating was employed as the S protective layer to improve the electrical conductivity and inhibit the shuttle effect. The results showed that the CISC prepared in this experiment had a relatively high specific surface area (1135.11 m2 g−1), and the S loading rate was as high as 65.72 %. The graded porous structure and high specific surface area of CISC can increase the loading rate of S and thus increase the battery capacity. Meanwhile, the naturally contained O and N elements can improve the chemisorption of S. The initial discharge capacity of the CISC@S/CNTs battery at 0.1 C is 967.3 mAh g−1, and the capacity retention rate is 74.3 % after 500 cycles. The unique composite structure improves the battery‘s electrical conductivity, reduces the dissolution of polysulfides, and enhances the battery cycle stability.
Subject
General Chemistry,Biochemistry,Organic Chemistry