Dual Pd‐Acid Sites Confined in a Hierarchical Core‐Shell Structure for Hydrogenation of Nitrobenzene-Reference-Cited by-同舟云学术

Dual Pd‐Acid Sites Confined in a Hierarchical Core‐Shell Structure for Hydrogenation of Nitrobenzene

Published:2023-09-20 Issue:21 Volume:18 Page:
ISSN:1861-4728
Container-title:Chemistry – An Asian Journal
language:en
Short-container-title:Chemistry An Asian Journal

Author:

Wang Yi‐Tian¹,Wu Si‐Ming¹,Luo Guo‐Qiang¹,Xiao Shi‐Tian¹,Pu Fu‐Fei¹,Wang Li‐Ying²,Chang Gang‐Gang¹,Tian Ge¹,Yang Xiao‐Yu¹^ORCID

Affiliation:

1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & International School of Materials Science and Engineering & School of Materials Science and Engineering & Shenzhen research institute of Wuhan University of Technology School of Chemistry Chemical Engineering and Life Science Wuhan University of Technology Wuhan 430071 P. R. China

2. Department State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics National Center for Magnetic Resonance in Wuhan Wuhan Institute of Physics and Mathematics Innovation Academy for Precision Measurement Science and Technology Chinese Academy of Sciences Wuhan 430071 P. R. China

Abstract

AbstractA core‐shell structured Pd@TS‐1@meso‐SiO2 catalyst with confined Pd nanometals has been fabricated by one‐pot synthesis, impregnation method and sol‐gel method. With the promotion of acid sites and protection of mesoporous silica shell, Pd@TS‐1@meso‐SiO2 shows higher activity than commercial comparison and higher stability than sample without mesoporous silica shell in the hydrogenation of nitrobenzene. The schematic illustration of the synergy effect is also proposed.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Basic and Applied Basic Research Foundation of Guangdong Province

Publisher

Wiley

Subject

General Chemistry,Biochemistry,Organic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/asia.202300689

Reference55 articles.

2. A Golden Boost to an Old Reaction

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