Affiliation:
1. Department of Chemistry and Advanced Material Chemistry Center (AMCC) Khalifa University, PO Box 127788 Abu Dhabi U.A.E.
2. Department of Chemistry Indian Institute of Technology Guwahati Guwahati 781039 India
Abstract
AbstractDirecting group assisted C−H bond functionalization using transition‐metal‐catalysis has emerged as a reliable synthetic tool for the construction of regioselective carbon‐carbon/heteroatom bonds. Off late, “in/on water directed transition‐metal‐catalysis”, though still underdeveloped, has appeared as one of the prominent themes in sustainable organic chemistry. This article covers the advancements, mechanistic insights and application of the sustainable directed C−H bond functionalization of (hetero)arenes in/on water in the presence of transition‐metal‐catalysis.
Subject
General Chemistry,Biochemistry,Organic Chemistry