Rechargeable Aqueous Zinc–Halogen Batteries: Fundamental Mechanisms, Research Issues, and Future Perspectives

Author:

She Liaona1,Cheng Hao234,Yuan Ziyan4,Shen Zeyu23,Wu Qian23,Zhong Wei24,Zhang Shichao2,Zhang Bing23,Liu Chengwu5,Zhang Mingchang1,Pan Hongge1,Lu Yingying1234ORCID

Affiliation:

1. Institute of Science and Technology for New Energy Xi'an Technological University Xi'an 710021 P. R. China

2. State Key Laboratory of Chemical Engineering Institute of Pharmaceutical Engineering College of Chemical and Biological Engineering Zhejiang University Hangzhou 310027 China

3. ZJU‐Hangzhou Global Scientific and Technological Innovation Center Zhejiang University Hangzhou 311215 China

4. Institute of Wenzhou Zhejiang University Wenzhou 325006 China

5. Department of Chemical Engineering Shanghai Jiao Tong University Shanghai 200240 P. R. China

Abstract

AbstractAqueous zinc–halogen batteries (AZHBs) have emerged as promising candidates for energy storage applications due to their high security features and low cost. However, several challenges including natural subliming, sluggish reaction kinetics, and shuttle effect of halogens, as well as dendrite growth of the zinc (Zn) anode, have hindered their large‐scale commercialization. In this review, first the fundamental mechanisms and scientific issues associated with AZHBs are summarized. Then the research issues and progresses related to the cathode, separator, anode, and electrolyte are discussed. Additionally, emerging research opportunities in this field is explored. Finally, ideas and prospects for the future development of AZHBs are presented. The objective of this review is to stimulate further exploration, foster the advancement of AZHBs, and contribute to the diversified development of electrochemical energy storage.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Publisher

Wiley

Subject

General Physics and Astronomy,General Engineering,Biochemistry, Genetics and Molecular Biology (miscellaneous),General Materials Science,General Chemical Engineering,Medicine (miscellaneous)

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