Odd and Even Numbered Ferric Wheels-Reference-Cited by-同舟云学术

Odd and Even Numbered Ferric Wheels

Published:2023-08-27 Issue:31 Volume:10 Page:
ISSN:2198-3844
Container-title:Advanced Science
language:en
Short-container-title:Advanced Science

Author:

Cutler Daniel J.¹^ORCID,Canaj Angelos B.¹^ORCID,Singh Mukesh K.¹^ORCID,Nichol Gary S.¹^ORCID,Gracia David²,Nojiri Hiroyuki³^ORCID,Evangelisti Marco²^ORCID,Schnack Jürgen⁴^ORCID,Brechin Euan K.¹^ORCID

Affiliation:

1. EaStCHEM School of Chemistry The University of Edinburgh David Brewster Road Edinburgh EH9 3FJ UK

2. Instituto de Nanociencia y Materiales de Aragón (INMA) CSIC & Universidad de Zaragoza Zaragoza 50009 Spain

3. Institute for Materials Research Tohoku University Katahira 2‐1‐1 Sendai 980–8577 Japan

4. Universität Bielefeld | Fakultät für Physik Postfach 100131 D‐33501 Bielefeld Germany

Abstract

AbstractThe structurally related odd and even numbered wheels [FeIII11ZnII4(tea)10(teaH)1(OMe)Cl8] (1) and [FeIII12ZnII4(tea)12Cl8] (2) can be synthesized under ambient conditions by reacting FeIII and ZnII salts with triethanolamine (teaH3), the change in nuclearity being dictated by the solvents employed. An antiferromagnetic exchange between nearest neighbors, J = ‐10.0 cm−1 for 1 and J = −12.0 cm−1 for 2, leads to a frustrated S = 1/2 ground state in the former and an S = 0 ground state in the latter.

Funder

Ministerio de Ciencia e Innovación

Japan Society for the Promotion of Science

Publisher

Wiley

Subject

General Physics and Astronomy,General Engineering,Biochemistry, Genetics and Molecular Biology (miscellaneous),General Materials Science,General Chemical Engineering,Medicine (miscellaneous)

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/advs.202304553

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