Exploring the influence of native minerals in coal gangue on CG/PE composite manufacturing and performance: Examining SiO2's role in interfacial compatibility

Abstract

AbstractThis study delves into the influence of inherent minerals within coal gangue (CG) on the preparation and performance of coal gangue /polyethylene (CG/PE) composites, focusing on the role of SiO2 in interfacial compatibility. A systematic examination unveils the consequences of varying SiO2 content on physical, mechanical, thermal, and microstructural attributes of the composites. SiO2 incorporation significantly improves physical properties, boosting density and hardness but impacting tensile strength negatively. It enhances bending strength and modulus while diminishing tensile strength. Judicious SiO2 addition enhances thermal stability, but excess SiO2 may compromise thermal decomposition. Microstructural analysis, including SEM and FTIR, elucidates SiO2‐PE interactions, primarily through physical entanglement. SiO2 introduction promotes more ordered PE molecular chain arrangements, elevating composite crystallinity. In summary, this study provides in‐depth insights into SiO2's mechanistic impact on CG/PE composite properties, laying a robust foundation for designing environmentally friendly composites. These findings hold promise for advancing sustainable materials science and engineering. Future research may explore SiO2 optimization for specific applications and synergistic effects with other fillers in composites.Highlights SiO2 greatly improves the properties of CG/PE composites with detailed exploration. Reveals the specific SiO2‐PE interaction mechanism for a better comprehension. Performs structural analysis via XRD with valuable findings presented. Promotes pioneering advancements in eco‐friendly materials with broad significance.