Strategy of Controlling Ru Particles Size for Regulating Cleavage Rate of C−C and C−O Bonds of Biomass Polyols to Enhance the Yield of Methane-Reference-Cited by-同舟云学术

Strategy of Controlling Ru Particles Size for Regulating Cleavage Rate of C−C and C−O Bonds of Biomass Polyols to Enhance the Yield of Methane

Published:2023-11-15 Issue:2 Volume:16 Page:
ISSN:1867-3880
Container-title:ChemCatChem
language:en
Short-container-title:ChemCatChem

Author:

Gu Chun¹²,Yu Weiqiang¹^ORCID,Zhao Hanqing¹³,Shi Song¹,Che Penghua¹,Xu Jie¹,Gao Jin¹

Affiliation:

1. State Key Laboratory of Catalysis Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian Liaoning 116023 P. R. China

2. University of Chinese Academy of Sciences Beijing 100049 P. R. China

3. College of Chemical Engineering Shenyang University of Chemical Technology Shenyang 110142 P. R. China

Abstract

AbstractA series of porous silica were prepared by alkyl‐trimethyl‐ammonium bromide with different carbon chain lengths (PS‐n, n corresponds to the carbon chain length). These templates carried out precise structure regulation of porous silica. The Ru particles supported on porous silica behaved in precisely controlled size according to the pore diameter. When used in the hydrogenolysis of biomass polyols, a higher methane yield was achieved over Ru/PS‐16. This result can be explained by the higher C2/C3 over Ru/PS‐16 than others.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis

Reference26 articles.

2. Dehydrogenation and aromatization of methane under non-oxidizing conditions

3. A Mercury-Catalyzed, High-Yield System for the Oxidation of Methane to Methanol

4. Production of Syngas by Direct Catalytic Oxidation of Methane

5. Catalytic conversion of methane to more useful chemicals and fuels: a challenge for the 21st century