Affiliation:
1. State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic Chemistry University of Chinese Academy of Sciences Shanghai 200032 P. R. China
2. School of Chemistry and Materials Science Hangzhou Institute for Advanced Study University of Chinese Academy of Sciences Hangzhou 310024 P. R. China
Abstract
AbstractBeyond the scope of classical Tsuji‐Trost reaction, an alkene bearing a remote leaving group is not considered as a potential substrate for allylation. The concept of migratory Tsuji‐Trost reaction focuses on the transformations with this type of substrates. Two pathways including olefin migration and leaving group migration to form typical allyl intermediate for following substitution have been explored to demonstrate the feasibility of this new concept.
Funder
Science and Technology Commission of Shanghai Municipality
National Natural Science Foundation of China
Natural Science Foundation of Ningbo Municipality
Shanghai Rising-Star Program
Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis