Affiliation:
1. Department of Chemistry and Center for Sustainable Chemistry Ghent University Krijgslaan 281 (S-3) 9000 Ghent Belgium
2. Faculty of Chemistry Adam Mickiewicz University in Poznań Uniwersytetu Poznańskiego St. 8 61–614 Poznań Poland
Abstract
AbstractThe environmentally friendly, simple synthesis of a family complexes of the general formula [NHC⋅H][Pd(NH2)(CC)Cl2] (CC=biphenyl) is presented. The catalytic activity of these air‐ and moisture‐stable complexes was evaluated as a function of the imidazolium counterion. These pre‐catalysts can be converted, under catalytic conditions, to Pd‐NHC species enabling the Suzuki–Miyaura, Sonogashira, and Buchwald–Hartwig amination reactions under very mild operating conditions.
Funder
Narodowa Agencja Wymiany Akademickiej
Bijzonder Onderzoeksfonds UGent
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis