Affiliation:
1. Department of Chemistry and Technology of Silicon Compounds Faculty of Chemistry Adam Mickiewicz University in Poznań Uniwersytetu Poznańskiego St. 8 61-614 Poznań Poland
Abstract
AbstractA cobalt‐catalyzed addition of hydrosilanes to unsaturated carbon‐oxygen bonds has been developed, relying on complexes featuring easily accessible and inexpensive PNP‐type pincer ligands. A wide range of heterocyclic, aliphatic, and aromatic ketones, including those containing both electron‐donating and electron‐withdrawing substituents, were transformed into silyl ethers or secondary alcohols with high yields. An important feature of this protocol is that silanes can act as both the substrates and activators, eliminating the need for external additives such as strong bases.
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis
Cited by
7 articles.
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