Recent Advances in Catalytic Conversion of 5‐Hydroxymethylfurfural (5‐HMF) to 2,5‐Dimethylfuran (2,5‐DMF): Mechanistic Insights and Optimization Strategies

Author:

Castillo Cristian1ORCID,Brijaldo Maria H.2ORCID,Silva Ludmila P. C.3ORCID,Passos Fabio B.3ORCID

Affiliation:

1. Escuela de Ciencias Químicas Grupo de Catálisis (GC-UPTC) Universidad Pedagógica y Tecnológica de Colombia UPTC 1500 Tunja Colombia

2. Escuela de Ciencias Administrativas y Económicas Grupo de investigación de Farmacia y Medio Ambiente (Farquima) Universidad Pedagógica y Tecnológica de Colombia UPTC 1500 Tunja Colombia

3. Departamento de Engenharia Química e de Petróleo Universidade Federal Fluminense 24210-240 Niterói Brazil

Abstract

AbstractThis review article describes the most recent studies carried out in the catalytic conversion of 5‐hydroxymethylfurfural (5‐HMF) in 2,5‐dimethylfurane (2,5‐DMF). In this way, the most novel catalytic materials are presented and their main results during 2,5‐DMF production through catalytic hydrogen transfer (CHT) by hydrogenation and hydrogenolysis reactions and through hydrodeoxygenation (HDO) reaction as commonly routes employed. Additionally, the optimized reaction conditions applying for each catalyst are discussed. Some future perspectives on the use of CHT and HDO processes in the 2,5‐DMF production from 5‐HMF as platform molecule in order to suggest new applications of pathways in the heterogeneous catalysis field are presented.

Funder

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Fundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro

Publisher

Wiley

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis

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