Organocatalytic Assembly Based on Aromatic Donor–Acceptor Interactions for the Asymmetric Aldol Reaction on Water-Reference-Cited by-同舟云学术

Organocatalytic Assembly Based on Aromatic Donor–Acceptor Interactions for the Asymmetric Aldol Reaction on Water

Published:2023-03-27 Issue:11 Volume:15 Page:
ISSN:1867-3880
Container-title:ChemCatChem
language:en
Short-container-title:ChemCatChem

Author:

Meso Garrett¹,Gregorich David¹,Waite Aya Jane¹,Smith Sam¹,Liu Linang²,Cortez Jacob¹,Harris Ender¹,Baluyut Rev Derek¹,Correa Natalia¹,Liang Jian¹,Liu Yu¹^ORCID

Affiliation:

1. Department of Chemistry Northern Michigan University 1401 Presque Isle Marquette MI-49855 USA

2. Capital Medical University NO.331 Xitieying Youanmen Fengtai District Beijing 100069 P. R. China

Abstract

AbstractAromatic donor modified prolinamide and aromatic acceptor modified thiourea were synthesized. They self‐assembled into a cooperative organocatalytic system through the aromatic donor‐acceptor interaction and catalyzed aldol reactions in high yields and stereoselectivity on water. The aromatic donor‐acceptor interaction was confirmed by mass spectrum, UV‐vis titraition and 1H‐NMR titration experiments.

Funder

American Chemical Society Petroleum Research Fund

Publisher

Wiley

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/cctc.202300012

Reference67 articles.

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