Visible‐Light‐Induced Insertion of Sulfur Dioxide Mediated by Electron Donor–Acceptor Complex: Synthesis and Photophysical Properties of 3‐Sulfonyl Indolizines-Reference-Cited by-同舟云学术

Visible‐Light‐Induced Insertion of Sulfur Dioxide Mediated by Electron Donor–Acceptor Complex: Synthesis and Photophysical Properties of 3‐Sulfonyl Indolizines

Published:2023-05-17 Issue:22 Volume:26 Page:
ISSN:1434-193X
Container-title:European Journal of Organic Chemistry
language:en
Short-container-title:Eur J Org Chem

Author:

Naud‐Martin Delphine¹²,Kosiuha Marharyta¹²,Zucolotto Cocca Leandro H.³^ORCID,Retailleau Pascal⁴,Mahuteau‐Betzer Florence¹²^ORCID,De Boni Leonardo³^ORCID,Piguel Sandrine⁵^ORCID

Affiliation:

1. Institut Curie Université PSL CNRS UMR9187, Inserm U1196 91400 Orsay France

2. Université Paris-Saclay CNRS UMR9187, Inserm U1196 91400 Orsay France

3. Instituto de Física de São Carlos Universidade de São Paulo CP 369 13560-970 São Carlos SP Brazil

4. Institut de Chimie des Substances Naturelles CNRS UPR 2301 Université Paris-Saclay 91198 Gif-sur-Yvette, cedex France

5. Université Paris-Saclay Faculté de Pharmacie CNRS UMR 8076 91400 Orsay France

Abstract

AbstractThis work investigates a light‐driven 3‐component sulfonylation reaction of indolizines without needing any external photocatalyst. The mechanistic investigations support the formation of an electron donor–acceptor (EDA) complex in situ. This transformation offers a mild and sustainable approach with high functional group tolerance for the synthesis of 3‐sulfonylated indolizines. This compound class has valuable photophysical properties and represents promising candidates in various applications related to fluorescence.

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

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