Photoinduced Metal‐Free Decarboxylative Transformations: Rapid Access to Amines, Alkyl Halides, and Olefins

Author:

Luo Jia‐jing1,Jing Dong1,Lu Cong1,Zheng Ke1ORCID

Affiliation:

1. Key Laboratory of Green Chemistry & Technology Ministry of Education College of Chemistry Sichuan University (P. R. China)

Abstract

AbstractHerein, we report an efficient photocatalytic strategy for the decarboxylative transformations of redox‐active esters to construct C=C, C(sp3)−N, and C(sp3)−X bonds in a single‐step. This operationally simple method provides a straightforward access to a variety of protected alkyl amines, alkyl halides and olefins under mild conditions in the absence of metals and photocatalysts. The method can successfully be applied to primary, secondary, and tertiary aliphatic carboxylic acid derivatives. Mechanistic studies indicate that the charge transfer complex (CTC) was formed by nBu4NI with redox‐active esters, in which the nBu4NI acted as both an iodine source and an efficient electron donor.

Funder

Ministry of Science and Technology

National Natural Science Foundation of China

Sichuan University

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Recent advancements in iodide/phosphine-mediated photoredox radical reactions;Beilstein Journal of Organic Chemistry;2023-11-22

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