Unexpected Formation of 2,2‐Dichloro‐ N ‐(chloromethyl)acetamides during Attempted Staudinger 2,2‐Dichloro‐β‐lactam Synthesis-Reference-Cited by-同舟云学术

Unexpected Formation of 2,2‐Dichloro‐ N ‐(chloromethyl)acetamides during Attempted Staudinger 2,2‐Dichloro‐β‐lactam Synthesis

Published:2021-11-10 Issue:42 Volume:2021 Page:5823-5830
ISSN:1434-193X
Container-title:European Journal of Organic Chemistry
language:en
Short-container-title:Eur. J. Org. Chem.

Author:

Deketelaere Sari¹^ORCID,Van Den Broeck Elias²^ORCID,Cools Lore¹,Deturck Daan¹,Naeyaert Hannes²,Van Hecke Kristof³^ORCID,Stevens Christian V.¹^ORCID,Van Speybroeck Veronique²,D'hooghe Matthias¹^ORCID

Affiliation:

1. SynBioC Research Group Department of Green Chemistry and Technology Faculty of Bioscience Engineering Ghent University Coupure Links 653 9000 Ghent Belgium

2. Center for Molecular Modeling Ghent University Technologiepark 46 9052 Zwijnaarde Belgium

3. XStruct Department of Chemistry Faculty of Sciences Ghent University Krijgslaan 281-S3 9000 Ghent Belgium

Funder

Universiteit Gent

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejoc.202100975

Reference40 articles.

1. Zur Kenntniss der Ketene. Diphenylketen

2. The Mechanism of the Ketene−Imine (Staudinger) Reaction in Its Centennial: Still an Unsolved Problem?

4. Origin of the Relative Stereoselectivity of the β-Lactam Formation in the Staudinger Reaction

5. Notable and Obvious Ketene Substituent-Dependent Effect of Temperature on the Stereoselectivity in the Staudinger Reaction

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