Recent Advances of 2‐Nitroglycals as Powerful Glycosyl Donors

Author:

Li Xinxin1,Deng Lei1,Wang Liming1,Zhang Qingju1ORCID

Affiliation:

1. Department: National Research Centre for Carbohydrate Synthesis Jiangxi Normal University 99 Ziyang Avenue Nanchang 330022 China

Abstract

Abstract2‐Nitroglycals are important synthons for biological active 2‐aminoglycosides, glycoconjugates and natural products synthesis. Herein, we summarized the recent advances of 2‐nitroglycals including its synthetic methods and its applications. Using 2‐nitroglycals, 2‐aminoglycosides, nitro‐polyol derivatives, sugar‐furan derivatives, sugar‐pyrrole molecules, 2,3‐diaminoglycosides and 2‐amino‐1,3‐dithioglycosides were obtained via Michael–type addition, retro‐Henry‐type reaction, C1/C3‐Ferrier rearrangement and [3+2] N‐heterocyclic addition. Most of these conversions are achieved via mild organo‐catalysis glycosylation methods.

Funder

National Natural Science Foundation of China

Jiangxi Provincial Department of Science and Technology

Publisher

Wiley

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