Affiliation:
1. Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences 100190 Beijing China
2. University of Chinese Academy of Sciences 100049 Beijing China
Abstract
AbstractThe exceptional versatility of carboxylic acids has been extensively exploited in organic synthesis across several decades. There has been a recent upsurge of radical decarboxylative transformations. The process can be initiated under mild conditions, and the resultant radicals have orthogonal reactivities to closed‐shell species, thus providing immense opportunities for streamlining novel reactions. The use of free carboxylic acids is the most desirable owing to its high atom and step economy. Aiming to demonstrate the attractiveness of the strategy and to inspire chemists to tackle existing challenges, this review outlines the recent advances on radical decarboxylative functionalization of free carboxylic acids.
Funder
National Natural Science Foundation of China
Chinese Academy of Sciences
Subject
Organic Chemistry,Physical and Theoretical Chemistry
Cited by
12 articles.
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