Affiliation:
1. Key Lab of Science and Technology of Eco-Textile Ministry of Education College of Chemistry and Chemical Engineering Donghua University Shanghai 201620 P. R. China
2. Key Laboratory of Tobacco Flavor Basic Research of CNTC Zhengzhou Tobacco Research Institute of CNTC Zhengzhou 450001 P. R. China
Abstract
AbstractA convenient PNP pincer manganese catalyzed transfer hydrogenation of bromides to corresponding debrominated aryl compounds using ethanol as the hydrogen sources is reported. Importantly, the application of biomass‐derived ethanol highlights the sustainability of the methodology. The use of 6‐phenyl substituted triazine‐based PiprN5Pipr manganese pincer catalyst allows for the debromination of various aryl bromides with good yields. Notably, the process also occurs with bromides derived from several classes of natural products and bioactive compounds, such as citronellol, diacetone fructose, cholesterol, and vitamin E.
Funder
Natural Science Foundation of Shanghai
National Natural Science Foundation of China
Subject
Organic Chemistry,Physical and Theoretical Chemistry
Cited by
1 articles.
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