Affiliation:
1. College of Chemistry and Chemical Engineering Yunnan Normal University Kunming 650500 P. R. China
2. The key Laboratory for Green Organic Synthesis and Application of Hunan Province Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education College of Chemistry Xiangtan University Xiangtan 411105 P. R. China
Abstract
AbstractA dioxygen‐triggered selectively difunctionalization of olefins to achieve β‐hydroxysulfones has been developed. Particularly, the mechanism of this reaction can be controlled by DABCO, which act as a single electron transfer reagent, to selectively obtain ketosulfone or hydroxysulfone. The reaction was conducted in a clean, safe, mild, and catalyst‐free conditions. Moreover, as a proof‐of‐concept, two bioactive molecules were synthesized easily using this method.
Funder
Natural Science Foundation of Hunan Province
Subject
Organic Chemistry,Physical and Theoretical Chemistry