Ag/K2S2O8‐Mediated Direct Thiolation and Selenylation of Carbazoles

Author:

Yin Jin1,Chen Peng1ORCID,Miao Le‐Wei1,Wang Jie2,Jiang Yi‐Jun1ORCID

Affiliation:

1. School of Materials Science and Chemical Engineering Institute of Drug Discovery Technology Ningbo University Ningbo 315211 P. R. China

2. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics Innovation Academy for Precision Measurement Science and Technology Chinese Academy of Sciences Wuhan 430071 P. R. China

Abstract

AbstractThe first direct and selective 3,6‐di‐thiolation and 3,6‐di‐selenylation of carbazoles using diaryl disulfides/diselenide as the sulfur/selenium source were demonstrated. This simple, general, and efficient method could deliver a wide range of 3,6‐di‐sulfenyl‐carbazoles and 3,6‐di‐selenyl‐carbazoles from readily available starting materials with high regioselectivity in an easily‐operated one‐step reaction via a Ag/K2S2O8‐mediated protocol.

Funder

Natural Science Foundation of Ningbo

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

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