Copper‐Catalyzed Fluoroamide‐Directed Remote C(sp3)‐H Bond Functionalization Through Intramolecular Hydrogen Atom Transfer

Author:

Lv Xin1,Yang Yuhao2,Zhou Liejin1,Zeng Xiaojun3ORCID

Affiliation:

1. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials College of Chemistry and Materials Science Zhejiang Normal University 688 Yinbing Rd Jinhua Zhejiang 321004 People's Republic of China

2. Department of Chemistry University of Louisville Louisville Kentucky 40292 United States

3. School of Chemistry and Chemical Engineering Nanchang University Nanchang Jiangxi 330031 People's Republic of China

Abstract

AbstractDirect C−H functionalization is an important strategy for the rapid synthesis of valuable organic molecules. Radical‐involved remote C(sp3)‐H functionalization based on hydrogen atom transfer (HAT) becomes an important method enabling selective direct transformation of C(sp3)‐H bonds at specific distal position(s). In the recent years, copper‐catalyzed fluoroamide‐directed remote C(sp3)‐H bond functionalization through intramolecular HAT has served as a robust and elegant strategy for the assembly of a variety of functionalized (sulfon)amides and related derivatives. This review focuses on the recent advances in this area. These transformations proceed effectively with high selectivities and good functional group compatibility under mild conditions.

Funder

Natural Science Foundation of Zhejiang Province

National Natural Science Foundation of China

Publisher

Wiley

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