Perfluoroalkylated Sulfoximines as Analogues of Togni Reagents: The Crucial Role of Fluorine Atoms for the Stability of Hypervalent Iodine Scaffolds-Reference-Cited by-同舟云学术

Perfluoroalkylated Sulfoximines as Analogues of Togni Reagents: The Crucial Role of Fluorine Atoms for the Stability of Hypervalent Iodine Scaffolds

Published:2023-11-22 Issue:47 Volume:26 Page:
ISSN:1434-193X
Container-title:European Journal of Organic Chemistry
language:en
Short-container-title:Eur J Org Chem

Author:

Duhail Thibaut¹,Kalim Jorna²^ORCID,Marrot Jérôme¹^ORCID,Pégot Bruce¹,Magnier Emmanuel¹^ORCID,Anselmi Elsa¹³^ORCID

Affiliation:

1. Université Paris-Saclay UVSQ CNRS UMR 8180 Institut Lavoisier de Versailles 78000 Versailles France

2. Swiss Federal Institute of Technology ETH Zurich Vladimir-Prelog-Weg 2 8093 Zurich Switzerland

3. Université de Tours Faculté des Sciences et Techniques 37200 Tours France

Abstract

AbstractHypervalent iodine compounds are described with perfluoroalkyl chains and S‐perfluoromethyl sulfoximines as ligands of the halogen. The influence of these groups on the stability of the cyclic structure is studied. The crucial role of the trifluoromethyl chain is clearly highlighted as an efficient ligand for the hypervalency. The structure and the reactivity of the new skeletons are discussed in detail.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Agence Nationale de la Recherche

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

Reference24 articles.

2. Novel 10-I-3 Hypervalent Iodine-Based Compounds for Electrophilic Trifluoromethylation

3. Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

4. Transition-Metal-Free Trifluoromethylaminoxylation of Alkenes

5. 1-Trifluoromethylisoquinolines from α-Benzylated Tosylmethyl Isocyanide Derivatives in a Modular Approach