Gold Microstructures by Thermolysis of Gold(III) Di‐isopropyldithiocarbamate Complexes

Author:

Angeloski A.12ORCID,Flower‐Donaldson K.23,Matar F.2,Hayes D. C.2,Duman M. N.2,Oldfield D. T.4ORCID,Westerhausen M. T.5ORCID,McDonagh A. M.2ORCID

Affiliation:

1. National Deuteration Facility Australian Nuclear Science Technology Organisation Sydney NSW Australia

2. School of Mathematical and Physical Sciences University of Technology Sydney NSW Australia

3. Minerals Australian Nuclear Science Technology Organisation Sydney NSW Australia

4. Nuclear Materials Development and Characterisation Australian Nuclear Science Technology Organisation Sydney NSW Australia

5. Hyphenated Mass Spectrometry Laboratory University of Technology Sydney NSW Australia

Abstract

AbstractElemental gold was formed by thermolysis of gold(III) dithiocarbamate single‐source precursors, which exist as two complexes. The complexes were readily synthesised from the reaction between chloroauric acid and sodium di‐isopropyldithiocarbamate and could be isolated from each other. The thermal decomposition processes were evaluated using thermogravimetry and electrical resistance measurements. The structure and purity of the resultant gold was examined using scanning electron microscopy. The resultant gold materials were drastically different and dependent on the thermolysed complex.

Publisher

Wiley

Subject

Materials Chemistry,Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Biomaterials

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