Affiliation:
1. Institute of Physical Chemistry and Electrochemistry Leibniz University Hannover Callinstraße 3a 30167 Hannover Germany
2. Cluster of Excellence PhoenixD Photonics, Optics, and Engineering – Innovation Across Disciplines) Leibniz University Hannover 30167 Hannover Germany
3. Laboratory for Nano and Quantum Engineering Leibniz University Hannover 30167 Hannover Germany
4. Institute of Physical Chemistry University of Hamburg Grindelallee 117 20146 Hamburg Germany
5. The Hamburg Centre for Ultrafast Imaging University of Hamburg Hamburg Germany
Abstract
AbstractCryogels have morphological features that make them interesting for several applications such as catalysis, sensing or tissue engineering. Their interconnected network and open porous structure, build up by primary particles (such as inorganic nanocrystals or polymers), provide these materials with unique physical properties and high specific surface areas. While the library of cryogels is endless, widely used in the polymer chemistry field, in this review we will summarize the structure and properties, applications and challenges of inorganic nanocrystal‐based cryogels obtained by freezing and freeze‐drying an aqueous nanoparticle colloid. This fast, easy and versatile gelation method will be outlined, along with the corresponding macro‐, micro‐ and nano‐structures and gel morphologies that can be obtained, for example, by changing the freezing temperature or by using one nanoparticle system or nanoparticle mixtures. Their applications towards electrocatalysis, photocatalysis and photoelectrochemical sensing will be highlighted, as well as the challenges and prospects of these materials.