Enhanced and Rapid Electro‐oxidation Degradation for Highly Concentrated Tetracycline by Mn Nanoparticle‐Doped NiAl‐LDHs

Author:

He Chifei12,Li Haoran12,Meng Weixu1,Li Jing3,Liu Wenjuan12ORCID,Xiao Ning4

Affiliation:

1. College of Materials Science and Engineering Nanjing Tech University Nanjing 211816 China

2. Jiangsu Collaborative Innovation Center for Advanced Inorganic Functional Composites Nanjing Tech University Nanjing 211816 China

3. Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering Zhejiang University Hangzhou 310027 China

4. College of Chemical Engineering Beijing University of Chemical Technology Beijing 100029 China

Abstract

AbstractAntibiotic pollution has posed a serious threat to water environments. To cope with this issue, layered double hydroxides (LDHs) have been employed and exhibited effective removability. However, most of LDHs adsorb antibiotics for water decontamination, which is difficult to degrade the pollutants and usually takes a quite long treatment time. In this work, Mn doped NiAl‐LDHs electrode was synthesized for antibiotic degradation with target pollutant tetracycline (TC). The removal efficiency of TC was then investigated by conducting electro‐oxidation with Mn doped NiAl‐LDHs anode. Specifically, some Mn doped NiAl‐LDHs nanoflowers were shed from NF substrate during the oxidation process, thus forming a 3D‐like electrode device and facilitating TC removal. Meanwhile, due to particle electrode‐like architecture and electro‐oxidation of the composite electrode, high concentration of TC can be removed quickly in a short time, and the removal efficiency can reach 92.6% in 5 min.

Funder

Natural Science Foundation of Jiangsu Province

Fundamental Research Funds for the Central Universities

Publisher

Wiley

Subject

Materials Chemistry,Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Biomaterials

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