Green synthesis of tellurium‐doped SnO2 nanoparticles with sulfurized g‐C3N4: Insights into methylene blue photodegradation and antibacterial capability

Author:

Umar Misbah1,Ajaz Humayun1,Javed Mohsin2,Mansoor Sana2,Iqbal Shahid3ORCID,Mahmood Sajid34,Rauf Abdul2,Aroosh Komal2,Bahadur Ali56,Alshalwi Matar7

Affiliation:

1. Department of Chemistry University of Engineering and Technology Lahore Lahore Pakistan

2. Department of Chemistry, School of Science University of Management and Technology Lahore Pakistan

3. Nottingham Ningbo China Beacons of Excellence Research and Innovation Institute University of Nottingham Ningbo China Ningbo China

4. Functional Materials Group Gulf University for Science and Technology Mishref Kuwait

5. Department of Chemistry, College of Science, Mathematics, and Technology Wenzhou‐Kean University Wenzhou China

6. Dorothy and George Hennings College of Science, Mathematics and Technology Kean University Newark New Jersey USA

7. Department of Chemistry, Collage of Science King Saud University Riyadh Saudi Arabia

Abstract

AbstractThe construction of SnO2 nanoparticles (NPs), specifically Te‐doped SnO2 NPs, using a simple and economical co‐precipitation technique has been thoroughly described in this work. NH3 served as the reducing agent in this procedure, whilst polyethylene glycol served as the capping agent. The primary goals of our work were to investigate the physicochemical properties of the synthesized SnO2 NPs and assess their potential use as antibacterial agents and photocatalysts. Scanning electron microscopy–energy dispersive X‐ray, ultraviolet light, Fourier transform infrared spectroscopy, X‐ray diffraction (XRD), and other analytical techniques were used to thoroughly analyze the NPs. Based on the full width at half maximum of the most noticeable peaks in the XRD spectrum, the Debye–Scherrer equation was used to calculate the crystallite sizes, which indicated the presence of a single tetragonal SnO2 phase. Particularly noteworthy was the exceptional photocatalytic activity of graphene‐assisted Te‐doped SnO2 NPs, achieving an impressive decomposition efficiency of up to 98% in the photo‐oxidation of methylene blue. Furthermore, our investigation delved into the antibacterial attributes of the synthesized SnO2 NPs against Escherichia coli and Staphylococcus aureus, demonstrating inhibitory effects on both bacteria strains. This suggests potential applications for these NPs in various environmental and medical contexts.

Funder

Wenzhou-Kean University

King Saud University

Publisher

Wiley

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