Carbon Quantum Dot Optical Properties for potential infiltration into Hollow Core Photonic Crystal Fibers

Author:

Arroyo Eurydice12,Tentori Diana1,Garcia Alfonso1,Valdez Ricardo3,Armenta Miguel A.4,Nava Osvaldo J.5,Machorro Roberto6,Olivas Amelia6ORCID

Affiliation:

1. Div. Física Aplicada Centro de Investigación Científica y de Educación Superior de Ensenada Carr. Tijuana‐Ensenada 3918, Zona Playitas 22860 Ensenada, Baja California Mexico

2. Departamento de Ingenieria Industrial Tecnológico Nacional de México/Instituto Tecnológico de Ensenada Blvd. Tecnológico #150, Ex Ejido Chapultepec 22780 Ensenada, Baja California Mexico

3. Centro de Graduados e Investigación en Química Tecnológico Nacional de México/Instituto Tecnológico de Tijuana Blvd. Industrial s/n, Cd Industrial 22430 Tijuana, Baja California Mexico

4. Departamento de Ingeniería en Geociencias Universidad Estatal de Sonora Av. Guerrero Sur 917 Magdalena de Kino Sonora 84160 Mexico

5. Facultad de Ingeniería Arquitectura y Diseño Universidad Autónoma de Baja California Carr. Tijuana‐Ensenada s/n, Zona Playitas 22860 Ensenada, Baja California Mexico

6. Centro de Nanociencias y Nanotecnología Universidad Nacional Autónoma de Mexico Carr. Tijuana‐Ensenada 3918, Zona Playitas 22860 Ensenada, Baja California Mexico

Abstract

AbstractCarbon quantum dots (CQD) have received significant attention in recent years due to their potential applications in optics and sensing. In this study, the authors report on the first characterization of the optical activity and broad absorption spectrum covering from short‐wave ultraviolet, at 200 nm, to mid‐infrared, at 1600 nm, of CQD synthesized using the “low‐molecular‐weight alcohols electrochemical carbonization” method. The CQD are analyzed using spectroscopic techniques, optical activity in the infrared, and high‐resolution transmission electron microscopy. Results show a CQD size distribution of 5±3 nm and spherical morphology. The absorption spectra show increased absorption at both, high and low frequency. Additionally, the specific rotation of the CQD solution is significantly higher than that of pure ethanol, by three orders of magnitude. These findings suggest that CQD may have potential applications in polarized infrared filters and/or sensors due to their ability to rotate the polarization state of light at 1550 nm. The results of this study provide valuable insights into the optical properties of CQD and their potential for infiltration into hollow core photonic crystal fibers, making them a promising material for future research and development in the field of optics and sensing.

Publisher

Wiley

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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