Revealing the Potential and Challenges of High‐Entropy Layered Cathodes for Sodium‐Based Energy Storage

Author:

Gao Hong1,Li Jiayi1,Zhang Fan1,Li Congcong1,Xiao Jun2,Nie Xinming3,Zhang Guilai1,Xiao Yang1,Zhang Dingyi1,Guo Xin2,Wang Yong1,Kang Yong‐Mook4,Wang Guoxiu5,Liu Hao5ORCID

Affiliation:

1. Joint International Laboratory on Environmental and Energy Frontier Materials School of Environmental and Chemical Engineering Shanghai University Shanghai 200444 China

2. Faculty of Materials Science and Energy Engineering Institute of Technology for Carbon Neutrality Shenzhen Institute of Advanced Technology Chinese Academy of Sciences Shenzhen Guangdong 518055 China

3. School of Physics and Electronic Engineering Jiangsu Normal University Xuzhou Jiangsu 221116 China

4. Department of Materials Science & Engineering Korea University Seoul 02841 Republic of Korea

5. Centre for Clean Energy Technology University of Technology Sydney Broadway Sydney NSW 2007 Australia

Abstract

AbstractSodium‐ion batteries (SIBs) reflect a strategic move for scalable and sustainable energy storage. The focus on high‐entropy (HE) cathode materials, particularly layered oxides, has ignited scientific interest due to the unique characteristics and effects to tackle their shortcomings, such as inferior structural stability, sluggish reaction kinetics, severe Jahn‐Teller effects induced lattice distortion, and poor oxygen reversibility at high voltage. This review focuses on high‐entropy oxide materials, highlighting their fundamentals, design principles, and application in layered oxide cathodes for SIBs. It delves into the growth mechanism, composition‐properties correlations, and the functional roles of high‐entropy design in enhancing the performance of layered oxide cathodes. Furthermore, it furnishes a comprehensive survey of recent advancements and persisting challenges within the domain of layered high‐entropy cathode materials, as well as offers insights into potential future research directions in line with the current state of knowledge.

Funder

State Key Laboratory of Advanced Special Steel

Shanghai University

Science and Technology Commission of Shanghai Municipality

Publisher

Wiley

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